The draw has been made for the Copa del Rey last 32, which sees La Liga clubs enter the competition for the first time this season.

Barcelona kick off their trophy defence against Segunda B side Villanovense, while Real Madrid face fellow third-tier outfit Cadiz, Los Blancos’ League rivals in 2005-06.

Elsewhere, there are four all-Primera ties, namely Real Betis-Sporting Gijon, Levante-Espanyol, Las Palmas-Real Sociedad and Rayo Vallecano-Getafe.

The first legs will be played on December 2, with the return fixtures a fortnight later.

However, Barca’s Club World Cup commitments mean they will play their tie over October 28 and December 2.

Copa del Rey last-32 draw in full:

Cadiz v Real Madrid

Villanovense v Barcelona

Barakaldo v Valencia

Reus v Atletico Madrid

UD Logrones v Sevilla

Balompedica Linense v Athletic Bilbao

Huesca v Villarreal

Almeria v Celta

Leganes v Granada

Llagostera v Deportivo La Coruna

Mirandes v Malaga

Ponferradina v Eibar

Real Betis v Sporting Gijon

Levante v Espanyol

Las Palmas v Real Sociedad

Rayo Vallecano v Getafe